Synthesis of azirines containing aldehyde functionality and their utilization as synthetic tools for five membered oxazoles and isoxazoles | Zendy

Brahma Sulagna | Zendy; Ray Jayanta K. | Zendy

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Synthesis of azirines containing aldehyde functionality and their utilization as synthetic tools for five membered oxazoles and isoxazoles

Author(s) -

Brahma Sulagna,

Ray Jayanta K.

Publication year - 2008

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570450203

Subject(s) - chemistry , aldehyde , ring (chemistry) , scope (computer science) , lewis acids and bases , catalysis , combinatorial chemistry , organic chemistry , programming language , computer science

A simple and useful procedure for the synthesis of azirines containing aldehyde functionality from open chain bromo/chloro‐aldehydes at room temperature is reported. The scope of the ring expansion reaction of a number of 3‐substituted‐2‐formyl‐azirines has been examined using different oraganometallic catalysts and a variety of Lewis acids.

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