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Synthesis, stereochemistry and adsorption studies of new spiranes and polyspiranes containing 1,2‐dithiolane units
Author(s) -
Gropeanu Radu A.,
Ţînţaş Mihaela L.,
Pilon Catherine,
Morin Mario,
Breau Livain,
Turdean Raluca,
Grosu Ion
Publication year - 2007
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570440303
Subject(s) - chemistry , dithiolane , monolayer , adsorption , stereochemistry , organic chemistry , biochemistry
The synthesis and stereochemistry of a series of new cyclic disulfides containing (poly)spirane 1,2‐dithiolane units are reported. Also included is a study of the self‐assembled monolayers ( SAMs ) of these compounds on a gold surface. The characteristics of the resultant SAMs were determined by IR spectroscopy using molecular mechanics calculations.