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Cycloaddition reactions with 2,3‐benzodiazepine derivatives
Author(s) -
Kertész Máriusz,
Pallagi István,
Sólyom Sándor
Publication year - 2007
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570440224
Subject(s) - chemistry , diazomethane , cycloaddition , nitrile , benzodiazepine , reactivity (psychology) , ring (chemistry) , 1,3 dipolar cycloaddition , medicinal chemistry , propargyl , double bond , organic chemistry , catalysis , medicine , biochemistry , receptor , alternative medicine , pathology
We report here on some 3+2 dipolar cycloaddition reactions of propargyl, allyl and cyano substituted 2,3‐benzodiazepines with in situ generated nitrile oxides and diazomethane. The reactivity of carbon‐nitrogen double bonds of the 5 H ‐[2,3]benzodiazepine ring system was also noticed.

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