In situ  preparation of rhodium/ n ‐heterocyclic carbene complexes and use for addition of arylboronic acids to aldehydes | Zendy

Kilinçarslan Rafet | Zendy; Çetinkaya Engin | Zendy; Çetinkaya Bekir | Zendy; Yiǧit Murat | Zendy; Özdemir İsmail | Zendy

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In situ preparation of rhodium/ n ‐heterocyclic carbene complexes and use for addition of arylboronic acids to aldehydes

Author(s) -

Kilinçarslan Rafet,

Çetinkaya Engin,

Çetinkaya Bekir,

Yiǧit Murat,

Özdemir İsmail

Publication year - 2007

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570440111

Subject(s) - chemistry , phenylboronic acid , carbene , rhodium , in situ , steric effects , organic chemistry , catalysis , medicinal chemistry , polymer chemistry

The in situ prepared three component system [RhCl(COD)] 2 /imidazolidinium salts ( 2, 4 ) and KOBu t catalyses the addition of phenylboronic acid to sterically hindered aldehydes affording the corresponding arylated secondary alcohols in good yields. Four novel 1,3‐dialkylimidazolidinium ( 2‐4 ) salts as NHC precursors were synthesized from N,N′ ‐dialkylethylenediamine.

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