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Application on novel fragmentation reaction: A concise synthesis of 2,3,5‐trisubstituted furans from butenolides
Author(s) -
Zhang Xuqing,
Jackson Elieen U.,
Schultz Arthur G.
Publication year - 2006
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570430135
Subject(s) - chemistry , reagent , fragmentation (computing) , aryl , alkyl , combinatorial chemistry , organic chemistry , computer science , operating system
AbstractButenolides 4 , generated from a novel fragmentation reaction, function as excellent precursors to 2,3,5‐trisubstituted furans 5 by additions of alkyl or aryl metallic reagents. It can also be converted into siloxyfurans 6 by treatment with silylating reagents.