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On the reactivity of isoxazoles with Mo(CO) 6
Author(s) -
Donati Donato,
Ferrini Serena,
Fusi Stefania,
Ponticelli Fabio
Publication year - 2004
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570410518
Subject(s) - chemistry , reactivity (psychology) , medicinal chemistry , stereochemistry , medicine , pathology , alternative medicine
Ring opening with molybdenum hexacarbonyl of functionalized isoxazoles is a valuable synthetic process. Tetrazolopyridine 4 and pyrazolopyridine 9 were obtained from isoxazolopyridines 3 and 6 , respectively, whereas the isoxazole 14 gave ketone 16 through the intermediate 17.