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Synthesis of homochiral 2‐ C ‐trifluoromethyl D‐and L‐ribose via trifluoromethylation of pentopyranosid‐2‐uloses
Author(s) -
Eilitz Uwe,
Böttcher Christoph,
Hennig Lothar,
Burger Klaus,
Haas Alois,
Gockel Simone,
Sieler Joachim
Publication year - 2003
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570400221
Subject(s) - trifluoromethylation , chemistry , trifluoromethyl , ribose , stereochemistry , medicinal chemistry , organic chemistry , enzyme , alkyl
Efficient syntheses of 2‐ C ‐trifluoromethyl D‐ and L‐ribose and some O ‐glycosides via trifluoromethylation of D‐ and L‐3,4‐ O ‐isopropylidene‐β‐ erythro ‐pentopyranosid‐2‐ulose with Ruppert's reagent are described.