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Synthesis of zincic phthalocyanine derivative functionalized with four peripheral tetrathiafulvalene units
Author(s) -
Hu Yingyu,
Shen Yongjia
Publication year - 2002
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570390535
Subject(s) - chemistry , tetrathiafulvalene , phthalocyanine , nmr spectra database , derivative (finance) , proton nmr , mass spectrum , solubility , solvent , fast atom bombardment , spectral line , stereochemistry , crystallography , molecule , mass spectrometry , organic chemistry , physics , chromatography , astronomy , financial economics , economics
A zincic phthalocyanine (Pc) derivative functionalized with four peripheral substituted tetrathiafulvalene (TTF) units has been synthesized. The intermediates and target compound have been characterized by 1 H‐nmr, 13 C‐nmr, ms, EA, uv‐vis and mp. The molecular weight of H 2 Pc‐TTF 4 can not be found in mass spectra. 1 H‐nmr spectra and mp determination show both H 2 PC‐TTF 4 and ZnPc‐TTF 4 are isomer‐mixtures. Uv‐vis spectra indicate that the aggregation of H 2 PC‐TTF 4 is solvent dependent and the introduction of Zn atom affects the solubility of the assembly.