Inverse‐electron demand [ π 2 +  σ 2 +  σ 2] cycloaddition reaction of dimethyl oxaquadricyclane‐2,3‐dicarboxylate with cyclooctyne | Zendy

Matsumoto Kiyoshi | Zendy; Taketsuna Hiroyuki | Zendy; Kim Jong Chul | Zendy; Kakehi Akikazu | Zendy

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Inverse‐electron demand [ π 2 + σ 2 + σ 2] cycloaddition reaction of dimethyl oxaquadricyclane‐2,3‐dicarboxylate with cyclooctyne

Author(s) -

Matsumoto Kiyoshi,

Taketsuna Hiroyuki,

Kim Jong Chul,

Kakehi Akikazu

Publication year - 2001

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570380535

Subject(s) - cycloaddition , chemistry , adduct , inverse , medicinal chemistry , stereochemistry , organic chemistry , catalysis , mathematics , geometry

A first example of an inverse‐electron demand [ π 2 + σ 2 + σ 2] cycloaddition reaction of dimethyl oxaquadricyclane‐2,3‐dicarboxylate was reported: cyclooctyne underwent cycloaddition with dimethyl oxaquadricyclane‐2,3‐dicarboxylate to afford the corresponding adducts one of whose structure was confirmed by a single crystal X‐ray analysis.

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