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Formation and cycloaddition reactions of ferrocenyl nitrones
Author(s) -
CoutouliArgyropoulou Evdoxia,
Sabbas Ioannis,
Konarski Stefan
Publication year - 2000
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570370505
Subject(s) - chemistry , cycloaddition , stereoselectivity , nitrone , pyrrolidinones , cleavage (geology) , ferrocene , organic chemistry , combinatorial chemistry , catalysis , geotechnical engineering , electrode , fracture (geology) , engineering , electrochemistry
Ferrocenyl nitrones derived from aldehydes or oximes react with electron deficient alkenes to give ferrocenylisoxazolidines. 5‐Methoxycarbonylisoxazolidines are further transformed to ferrocenyl‐pyrrolidinones by reductive cleavage. The regio‐ and stereoselectivity of the reactions are discussed.