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Diastereoselective alkylation of acetoacetates of chiral inductors. Synthetic applications
Author(s) -
Gálvez N.,
MorenoMañas M.,
Sebastián R. M.,
Serra N.,
Trepat E.,
Vallribera A.,
Molins E.
Publication year - 2000
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570370437
Subject(s) - chemistry , alkylation , combinatorial chemistry , organic chemistry , stereochemistry , catalysis
Diastereoselective alkylations of acetoacetates of chiral inductors are reviewed. The formed products are starting materials for the preparation of enantiomerically pure amino acids, 4,4‐disub‐stituted 2‐pyrazolin‐5‐ones, and of oxazoles and pyrazoles incorporating the chiral inductors.