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2,4,6‐Triphenylpyridine as a neutral leaving group in the palladium(0)‐catalyzed allylation of nucleophiles
Author(s) -
MorenoMañas M.,
Mortal L.,
Pleixats R.
Publication year - 1997
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570340136
Subject(s) - chemistry , nucleophile , palladium , dimethyl malonate , morpholine , leaving group , reagent , catalysis , medicinal chemistry , malonate , group (periodic table) , organic chemistry
Palladium(0)‐catalyzed allylation of nucleophiles such as morpholine, sodium dimethyl malonate and 2,6‐dimethylaniline can be achieved under very mild conditions using N ‐allyl‐2,4,6‐triphenylpyridinium tetrafluoroborates as allylating reagents in reactions in which 2,4,6‐triphenylpyridine acts as the neutral leaving group.