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Azadiene diels‐alder reactions: Scope and applications. Total synthesis of natural and Ent ‐fredericamycin A
Author(s) -
Boger Dale L.
Publication year - 1996
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570330508
Subject(s) - chemistry , total synthesis , cycloaddition , sulfonyl , scope (computer science) , diels–alder reaction , organic chemistry , catalysis , alkyl , computer science , programming language
A review of our studies of the inverse electron demand Diels‐Alder reactions of heteroaromatic and acyclic azadienes is presented and the application of a N ‐sulfonyl‐1‐aza‐1,3‐butadiene [4+2] cycloaddition reaction in the total synthesis of natural and ent ‐fredericamycin A is described in detail.