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A trilactone related to anemonin
Author(s) -
Stamos Ioannis K.,
Cassady John M.
Publication year - 1996
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570330376
Subject(s) - chemistry , anhydrous , sodium carbonate , cleavage (geology) , iodine , carbonate , sodium , medicinal chemistry , hydrogen , ion , potassium carbonate , organic chemistry , geotechnical engineering , fracture (geology) , engineering
Treatment of Anemonin sequentially with two equivalents of the anion 2 and iodine gave the monoalkylated monoiodinated iodolactone t ‐butyl ester 3 . Ester cleavage in anhydrous acedic media followed by treatment with sodium hydrogen carbonate transformed 3 to trilactone 4 .
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