Polycyclic arene sulfides. Preparation of 1a,2,3,11b‐tetrahydrobenz‐[5,6]anthra[1,2‐ b ]thiirene, 6b,7a,8,9‐tetrahydrobenzo[10,11]‐chryseno[1,2‐ b ]thiirene, and 7,8,8a,9a‐tetrahydrobenzo‐[10,11]chryseno[3,4‐ b ]thiirene | Zendy

Shalom Yosef | Zendy; Kogan Vladimir | Zendy; Badriah Yacoub | Zendy; Harvey Ronald G. | Zendy

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Polycyclic arene sulfides. Preparation of 1a,2,3,11b‐tetrahydrobenz‐[5,6]anthra[1,2‐ b ]thiirene, 6b,7a,8,9‐tetrahydrobenzo[10,11]‐chryseno[1,2‐ b ]thiirene, and 7,8,8a,9a‐tetrahydrobenzo‐[10,11]chryseno[3,4‐ b ]thiirene

Author(s) -

Shalom Yosef,

Kogan Vladimir,

Badriah Yacoub,

Harvey Ronald G.

Publication year - 1996

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570330110

Subject(s) - chemistry , trifluoroacetic acid , anthracene , pyrene , catalysis , medicinal chemistry , organic chemistry , stereochemistry

The title compounds 5, 7 and 9 which are the first arene sulfides of 7,8‐dihydrobenz[ a ]anthracene, 8,9‐and 10,11‐dihydrobenzo[ a ]pyrene, respectively, have been synthesized by treatment of the corresponding arene oxides 4, 6 and 8 with N,N ‐dimethylthioformamide in the presence of catalytic amounts of trifluoroacetic acid.

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