A convenient synthesis of diaminoglyoxime and diaminofurazan: Useful precursors for the synthesis of high density energetic materials | Zendy

Gunasekaran Ananthakrishnan | Zendy; Jayachandran Thiruvalam | Zendy; Boyer Joseph H. | Zendy; Trudell Mark L. | Zendy

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A convenient synthesis of diaminoglyoxime and diaminofurazan: Useful precursors for the synthesis of high density energetic materials

Author(s) -

Gunasekaran Ananthakrishnan,

Jayachandran Thiruvalam,

Boyer Joseph H.,

Trudell Mark L.

Publication year - 1995

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570320452

Subject(s) - chemistry , potassium hydroxide , hydroxylamine hydrochloride , yield (engineering) , dehydration , derivative (finance) , sodium hydroxide , aqueous solution , hydrochloride , hydroxylamine , potassium , hydroxide , organic chemistry , nuclear chemistry , biochemistry , materials science , economics , financial economics , metallurgy

The reaction of glyoxime ( 4 ) and hydroxylamine hydrochloride in aqueous sodium hydroxide was found to be a safe and inexpensive method for the preparation of multigram quantities of diaminoglyoxime ( 5 ). Potassium hydroxide mediated dehydration of 5 furnished diaminofurazan ( 1 ) in good yield of exceptional purity. The ready availability of 1 and 5 has facilitated the synthesis of new energetic furazan derivative 8 .

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