A study of the photochemically induced electron‐transfer reactions between pyridinedicarbonitriles and primary and secondary aliphatic amines | Zendy

Bernardi Rosanna | Zendy; Caronna Tullio | Zendy; Poggi Gabriella | Zendy; Vittimberga Bruno M. | Zendy

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A study of the photochemically induced electron‐transfer reactions between pyridinedicarbonitriles and primary and secondary aliphatic amines

Author(s) -

Bernardi Rosanna,

Caronna Tullio,

Poggi Gabriella,

Vittimberga Bruno M.

Publication year - 1994

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570310436

Subject(s) - chemistry , primary (astronomy) , electron transfer , electron , photochemistry , computational chemistry , basis set , acceptor , basis (linear algebra) , electron acceptor , density functional theory , nuclear physics , physics , astronomy , condensed matter physics , geometry , mathematics

A study on the photochemically induced electron‐transfer from primary and secondary aliphatic amines as donors to pyridinedicarbonitriles as the acceptor is reported. A comparison between the substitution positions and the spin density distributions, obtained via theoretical calculations using the 6‐31+G basis set, shows some discrepancies, and forms the basis of a hypothesis on the mechanism of the reaction.

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