Enzymatic resolution of 4‐methyl‐, 4‐phenyl‐ and 6‐phenyltetrahydro‐2 H ‐pyran‐2‐one using esterases | Zendy

Izumi Taeko | Zendy; Tamura Futoshi | Zendy; Akutsu Mitsuyo | Zendy

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Enzymatic resolution of 4‐methyl‐, 4‐phenyl‐ and 6‐phenyltetrahydro‐2 H ‐pyran‐2‐one using esterases

Author(s) -

Izumi Taeko,

Tamura Futoshi,

Akutsu Mitsuyo

Publication year - 1994

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570310233

Subject(s) - chemistry , pyran , esterase , enantioselective synthesis , hydrolysis , optically active , resolution (logic) , enzyme , stereochemistry , enzymatic hydrolysis , organic chemistry , catalysis , artificial intelligence , computer science

Enantioselective hydrolysis of racemic tetrahydro‐2 H ‐pyran‐2‐ones (δ‐valerolactones) using esterase resulted in the formation of optically active ( R )‐4‐methyl‐, ( R )‐4‐phenyl‐ or ( R )‐6‐phenyltetrahydro‐2 H ‐pyran‐2‐ones and the corresponding ( S )‐8‐hydroxypentanoic acid derivatives.

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