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Photochemical reactivity of 9‐vinyladenine with diethyl fumarate
Author(s) -
D'Auria Maurizio,
Vantaggi Anna
Publication year - 1994
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570310220
Subject(s) - chemistry , dimethyl fumarate , epimer , reactivity (psychology) , photochemistry , organic chemistry , medicinal chemistry , medicine , psychology , alternative medicine , pathology , psychiatry , multiple sclerosis
The photochemical reaction between 9‐vinyladenine ( 2 ) and diethyl fumarate ( 4 ) gave an unusual photoadduct, epimers 4 and 5 , probably derived from attack of the vinyl group on N‐3 and reaction of diethyl fumarate on N‐9 and N‐6.