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Facile synthesis of 2‐[1‐(alkylthio)alkyl]pyridines and phenyl‐substituted derivatives
Author(s) -
Kiselyov Alexander S.,
Strekowski Lucjan,
Semenov Victor V.
Publication year - 1993
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570300206
Subject(s) - chemistry , tetrafluoroborate , alkyl , medicinal chemistry , organic chemistry , catalysis , ionic liquid
The title compounds 5 are produced in the reaction of N ‐fluoropyridinium tetrafluoroborate ( 1 ) with sulfides 2 . The proposed mechanism involves single‐electron transfer from 2 to 1 followed by transformations of the resultant radical intermediates.