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The structure of the CT complex between 5,7,12,14‐tetramethoxydibenzo[ b,i ]thianthrene with TCNQ
Author(s) -
Matsuoka Masaru,
Iwamoto Akihiro,
Ouchi Takeshi,
Yoshioka Hiroshi,
Nakatsu Kazumi
Publication year - 1993
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570300131
Subject(s) - thianthrene , chemistry , thiazole , intermolecular force , ring (chemistry) , crystallography , charge (physics) , stereochemistry , molecule , medicinal chemistry , organic chemistry , physics , quantum mechanics
The structure of 1,4‐dithiines obtained from orthodihalogeno heterocycles with thiocarbonyl compounds was determined by X‐ray structure analysis of the intermolecular charge‐transfer complex between 5,7,12,14‐tetramethoxydibenzo[ b,i ]thianthrene and TCNQ. The formation of the thiazole ring has already been reported but the products were confirmed to be 1,4‐dithiines by X‐ray structure analysis and the previously reported results.