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Synthesis of molybdenum(V) and molybdenum(VI) derivatives of 5,15‐diphenyl‐2,8,12,18‐tetra‐n‐butyl‐3,7,13,17‐tetramethylporphyrin
Author(s) -
Van Dijk Marinus,
Morita Yashuo,
Petrović Slobodan,
Sanders Georgine M.,
Van Der Plas Henk C.,
Stam Casper H.,
Wang Yuanfang
Publication year - 1992
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570290113
Subject(s) - chemistry , molybdenum , tetra , porphyrin , medicinal chemistry , mass spectrum , nuclear chemistry , inorganic chemistry , organic chemistry , ion
The methoxo‐oxomolybdenum(V), diperoxomolybdenum(VI) and cis ‐dioxomolybdenum(VI) derivatives of 5,15‐diphenyl‐2,8,12,18‐tetra‐ n ‐butyl‐3,7,13,17‐tetramethylporphyrin ( 4a, 5c, 6a ) have been prepared and characterized by uv, ir, pmr, mass and esr spectra. The structure of the molybdenum(V) porphyrin was confirmed by X‐ray analysis.