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Synthesis of vertical‐type bis(pyridodipyrimidines) as a redox catalyst and their autorecycling oxidation of alcohols
Author(s) -
Yamato Hirotake,
Nagamatsu Tomohisa,
Yoneda Fumio
Publication year - 1991
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570280509
Subject(s) - chemistry , redox , acetic acid , catalysis , condensation , alcohol oxidation , medicinal chemistry , organic chemistry , menthol , physics , thermodynamics
Condensation of bis(3‐methyluracil‐6‐ylamino)alkanes with 6‐chloro‐5‐formyl‐3‐methyluracil or 2,4,6‐trichloropyrimidine‐5‐carbaldehyde in acetic acid gave the respective bis(pyridodipyrimidin‐10‐yl)alkanes (vertical‐type bis(pyridodipyrimidines)). The vertical‐type bis(pyridodipyrimidines) exhibited autorecycling turnover oxidation toward cyclopentanol and l ‐menthol to give the corresponding carbonyl compounds.