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Identification, synthesis and conformational study of a CN( R,S ) synthon by‐product: (5 R , 10 R )‐5,10‐diphenyl‐1,6‐diaza‐3,8‐dioxabicyclo[4.4.1]undecane
Author(s) -
Aitken David J.,
Guillaume Dominique,
Husson HenriPhilippe,
Chiaroni Angèle,
Riche Claude
Publication year - 1991
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570280326
Subject(s) - chemistry , synthon , product (mathematics) , condensation , formaldehyde , molecule , stereochemistry , crystallography , organic chemistry , physics , geometry , mathematics , thermodynamics
The title compound, containing a new heterocyclic skeleton, was identified by X‐ray crystallography as the product of condensation of ( R )‐phenylglycinol with an excess of formaldehyde. The molecule adopts a rigid double twist‐chair conformation in both solid and solution states.