Identification, synthesis and conformational study of a CN( R,S ) synthon by‐product: (5 R , 10 R )‐5,10‐diphenyl‐1,6‐diaza‐3,8‐dioxabicyclo[4.4.1]undecane | Zendy

Aitken David J. | Zendy; Guillaume Dominique | Zendy; Husson HenriPhilippe | Zendy; Chiaroni Angèle | Zendy; Riche Claude | Zendy

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Identification, synthesis and conformational study of a CN( R,S ) synthon by‐product: (5 R , 10 R )‐5,10‐diphenyl‐1,6‐diaza‐3,8‐dioxabicyclo[4.4.1]undecane

Author(s) -

Aitken David J.,

Guillaume Dominique,

Husson HenriPhilippe,

Chiaroni Angèle,

Riche Claude

Publication year - 1991

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570280326

Subject(s) - chemistry , synthon , product (mathematics) , condensation , formaldehyde , molecule , stereochemistry , crystallography , organic chemistry , physics , geometry , mathematics , thermodynamics

The title compound, containing a new heterocyclic skeleton, was identified by X‐ray crystallography as the product of condensation of ( R )‐phenylglycinol with an excess of formaldehyde. The molecule adopts a rigid double twist‐chair conformation in both solid and solution states.

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