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The synthesis of substituted 2,3‐dihydrothieno[2,3‐ b ]‐thiophenes via intramolecular michael addition
Author(s) -
Williams Theresa M.,
Hudcosky Ronald J.,
Hunt Cecilia A.,
Shepard Kenneth L.
Publication year - 1991
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570280103
Subject(s) - chemistry , intramolecular force , michael reaction , thiophene , ring (chemistry) , combinatorial chemistry , stereochemistry , medicinal chemistry , organic chemistry , catalysis
The first regiospecific synthesis of the 2,3‐dihydrothieno[2,3‐ b ]thiophene ring system was achieved using an intramolecular Michael addition in the key cyclization step. This strategy represents a novel and potentially general method for dihydrothiophene and dihydrothiophene S,S ‐dioxide annellation.

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