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Stereoselective synthesis and stereochemical determination of 2,5‐dialkylpyrrolidines and 2,6‐dialkylpiperidines
Author(s) -
Bacos D.,
Célérier J. P.,
Marx E.,
Rosset S.,
Lhommet G.
Publication year - 1990
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570270538
Subject(s) - chemistry , stereoselectivity , alkyl , stereochemistry , organic chemistry , combinatorial chemistry , catalysis
ω‐Alkyllactams 3 can be transformed into ω‐alkyl cyclic β‐enaminoesters 7 which are good precursors of insects venom alkaloids. A stereoselective synthesis of dialkylpyrrolidines and Solenopsine A is described followed by an easy stereochemical determination by 13 C nmr.
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