Synthesis, structural and conformational study of 6‐hydroxy (or acyloxy) derivatives of the 1,3‐dimethyl‐1,3‐diazoniatricyclo[3.3.1.1 3–7 ]decane system | Zendy

Fernández M. J. | Zendy; Gálvez E. | Zendy; Lorente A. | Zendy; Camuñas J. A. | Zendy; Sanz J. | Zendy; Fonseca I. | Zendy

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Synthesis, structural and conformational study of 6‐hydroxy (or acyloxy) derivatives of the 1,3‐dimethyl‐1,3‐diazoniatricyclo[3.3.1.1 3–7 ]decane system

Author(s) -

Fernández M. J.,

Gálvez E.,

Lorente A.,

Camuñas J. A.,

Sanz J.,

Fonseca I.

Publication year - 1990

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570270533

Subject(s) - chemistry , decane , adamantane , ring (chemistry) , nuclear magnetic resonance spectroscopy , stereochemistry , crystal structure , crystallography , carbon 13 nmr , organic chemistry

1,3‐Dimethyl‐1,3‐diazoniatricyclo[3.3.1.1 3–7 ]decan‐6‐ol, and his p ‐chlorobenzoxy and diphenylacetoxy derivatives have been synthesized and studied by 1 H and 13 C nmr spectroscopy. The crystal structure of the alcohol 2a has been determined by X‐ray diffraction. Each ring of the adamantane cage system is a nearly perfect chair. From the 1 H and 13 C nmr data, several stereoelectronic effects have been deduced.

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