Picryl derivatives of 5‐nitro‐2,4‐dihydro‐3 H ‐1,2,4‐triazol‐3‐one | Zendy

Coburn Michael D. | Zendy; Lee KienYin | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Picryl derivatives of 5‐nitro‐2,4‐dihydro‐3 H ‐1,2,4‐triazol‐3‐one

Author(s) -

Coburn Michael D.,

Lee KienYin

Publication year - 1990

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570270318

Subject(s) - chemistry , nitro , derivative (finance) , medicinal chemistry , stereochemistry , organic chemistry , alkyl , financial economics , economics

Treatment of 5‐nitro‐2,4‐dihydro‐3 H ‐1,2,4‐triazol‐3‐one ( 1 ) with picryl fluoride (PkF) in 1‐methyl‐2‐pyrrolidinone (NMP) gave a mixture of a monopicryl and a dipicryl derivative of 1 in a ratio of 2 :1 , respectively, regardless of the initial concentrations of 1 and PkF. The products were identified as 5‐nitro‐2‐picryl‐2,4‐dihydro‐3 H ‐1,2,4‐triazol‐3‐one ( 2 ) by X‐ray crystallography and 5‐nitro‐2,4‐dipicryl‐2,4‐dihydro‐3 H ‐1,2,4‐triazol‐3‐one ( 4 ) by 15 N labeling experiments.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research