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FAB‐Induced deprotonation, elimination and decomposition of 1,3‐dithiolane S ‐oxides
Author(s) -
Bortolini O.,
Traldi P.
Publication year - 1990
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570270239
Subject(s) - chemistry , deprotonation , decomposition , reactivity (psychology) , dithiolane , gas phase , molecule , ion , computational chemistry , phase (matter) , medicinal chemistry , organic chemistry , medicine , alternative medicine , pathology
The gas‐phase unimolecular decomposition of [M‐H] − of 1,3‐dithiolane S ‐oxides has been studied using Fast Atom Bombardment (FAB) for anion generation. A comparison with the reactivity in solution is made and some differences or similarities with the chemistry in the gas‐phase are discussed. The decomposition pathways of the molecules under investigation are function of the substituents.