Reactions of furazano[3,4‐ b ]quinoxalines with phosphorus ylides and an unusual oxidative transformation of the transylidation product | Zendy

Gallos John K. | Zendy; Lianis Pygmalion S. | Zendy; Nicolaides Demetrios N. | Zendy

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Reactions of furazano[3,4‐ b ]quinoxalines with phosphorus ylides and an unusual oxidative transformation of the transylidation product

Author(s) -

Gallos John K.,

Lianis Pygmalion S.,

Nicolaides Demetrios N.

Publication year - 1989

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570260534

Subject(s) - chemistry , yield (engineering) , furan , phosphorus , derivative (finance) , oxidative phosphorylation , medicinal chemistry , transformation (genetics) , organic chemistry , product (mathematics) , biochemistry , materials science , economics , financial economics , metallurgy , gene , geometry , mathematics

Reactions of furazano[3,4‐ b ]quinoxalines 1 with phosphorus ylides 2 afford the transylidation product 3 and/or 4,9‐dihydrofurazano[3,4‐ b ]quinoxalines 4. Oxidation of 3 with phenyliodide bis‐trifluoroacetate gave the fused furan derivative 13 in high yield.

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