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Meso ‐[2.2]paracyclophanyltriphenylporphyrin: A simple representative of cyclophanylporphyrins
Author(s) -
Czuchajowski Leszek,
Goszczynski Stefan,
Wheeler Dale E.,
Wisor Antoni K.,
Malinski Tadeusz
Publication year - 1988
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570250643
Subject(s) - chemistry , porphyrin , moiety , simple (philosophy) , electrochemistry , tetra , combinatorial chemistry , computational chemistry , stereochemistry , polymer chemistry , photochemistry , medicinal chemistry , electrode , philosophy , epistemology
( R + S ) Meso ‐[2.2]Paracyclophanyltriphenylporphyrin 3 , a member of a novel class of cyclophanylporphyrins, was obtained and characterized by spectroscopic and electrochemical methods. Compared to meso ‐tetra[2.2]paracyclophanylporphyrin 1, it represents a simplified structure designed for the investigation of electronic interactions between the [2.2]paracyclophane moiety and porphyrin core and for use in metallation reactions.
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