The 2,1‐benzisothiazolo[2,3‐ b ]‐2,1‐benzisothiazole system, synthesis and properties | Zendy

Mckin David M. | Zendy; Duncan K. Ann | Zendy

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The 2,1‐benzisothiazolo[2,3‐ b ]‐2,1‐benzisothiazole system, synthesis and properties

Author(s) -

Mckin David M.,

Duncan K. Ann

Publication year - 1988

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570250409

Subject(s) - chemistry , hypervalent molecule , acetylation , amide , derivative (finance) , sulfur , methylation , stereochemistry , medicinal chemistry , organic chemistry , reagent , biochemistry , dna , financial economics , economics , gene

2,2′‐Diaminodiphenylmethane and its 4,4′‐dibromo‐derivative both react with N ‐sulfinylmethanesulfon‐amide to form 2,1‐benzisothiazole derivatives. Methylation or acetylation of these provides examples of the hypervalent sulfur 2,1‐benzisothiazolo[2,3‐ b ]‐2,1‐benzisothiazole system. The nmr spectra of these compounds are discussed.

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