Flavonoids.  41  . Stereospecific synthesis of 2,3‐dihydro‐ c ‐3‐substituted‐ t ‐3‐methyl‐ r ‐2‐phenyl‐4 H ‐1‐benzopyran‐4‐ones | Zendy

Patonay Tamás | Zendy; PatonayPéli Erzsébet | Zendy; Litkei György | Zendy; Szilágyi László | Zendy; Batta Gyula | Zendy; Dinya Zoltán | Zendy

Premium

Flavonoids. 41 . Stereospecific synthesis of 2,3‐dihydro‐ c ‐3‐substituted‐ t ‐3‐methyl‐ r ‐2‐phenyl‐4 H ‐1‐benzopyran‐4‐ones

Author(s) -

Patonay Tamás,

PatonayPéli Erzsébet,

Litkei György,

Szilágyi László,

Batta Gyula,

Dinya Zoltán

Publication year - 1988

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570250158

Subject(s) - chemistry , stereospecificity , benzopyran , nucleophile , mesylate , stereochemistry , medicinal chemistry , organic chemistry , catalysis

The synthesis of 2,3‐dihydro‐ t ‐3‐mesyloxy‐c‐3‐methyl‐ r ‐2‐phenyl‐4 H ‐1‐benzopyran‐4‐one (1) is described. The reaction of mesylate 1 with various nucleophiles, first of all O ‐ and N ‐nucleophiles, yields the corresponding 2,3‐dihydro‐ c ‐3‐substituted‐ t ‐3‐methyl‐ r ‐2‐phenyl‐4 H ‐1‐benzopyran‐4‐ones 2b, 7b, 9, 10, 12, 14 and 18 . Azide 14 is a useful intermediate for the synthesis of flavonoids 15–17 .

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research