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Synthesis and structure determination of N ‐(alkoxycarbonylsulfenyl)‐ s ‐triazine herbicides
Author(s) -
Pilgram K. H.,
Gale Laird H.
Publication year - 1988
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570250129
Subject(s) - chemistry , steric effects , triazine , solid state , group (periodic table) , stereochemistry , medicinal chemistry , crystallography , organic chemistry
Various 2‐substituted‐4,6‐bis(alkylamino)‐1,3,5‐triazines, 1 , have been found to react with alkoxycarbonylsulfenyl chlorides, 2 , to give the title compounds, 3 . The structural characterization of 3a in the solid state by single X‐ray crystallographic analysis established that it is the isomer wherein the methoxycarbonylthio group is attached to the less sterically hindered, exocyclic nitrogen bearing the ethyl group.