On the nitro group transfer from 2‐nitro‐4,5,6,7‐tetrachloro‐2 H ‐benzotriazole and 2‐nitro‐2 H ‐phenanthro[9,10‐ d ]triazole to secondary amines | Zendy

CohenFernandes Pauline | Zendy; Habraken Clarisse L. | Zendy

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On the nitro group transfer from 2‐nitro‐4,5,6,7‐tetrachloro‐2 H ‐benzotriazole and 2‐nitro‐2 H ‐phenanthro[9,10‐ d ]triazole to secondary amines

Author(s) -

CohenFernandes Pauline,

Habraken Clarisse L.

Publication year - 1987

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570240630

Subject(s) - nitro , chemistry , benzotriazole , morpholine , medicinal chemistry , 1,2,4 triazole , group (periodic table) , stereochemistry , organic chemistry , alkyl

The synthesis of 2‐nitro‐4,5,6,7‐tetrachloro‐2 H ‐benzotriazole 1 and of 2‐nitro‐2 H ‐phenanthro[9,10‐ d ]‐triazole 2 and their transfer of the nitro group to give 1‐nitropyrrolidine 4a and 1‐nitromorpholine 4b in high yields when reacted with pyrrolidine or morpholine are reported. The reaction of 1 also gives the pyrrolidinium and morpholinium salts 5a‐b of 1 .

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