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Photochemical intramolecular nitrene insertion of 6‐azidouridine derivatives
Author(s) -
Miyasaka Tadashi,
Tanaka Hiromichi,
Satoh Kazue,
Imahashi Mie,
Yamaguchi Kentaro,
Iitaka Yoichi
Publication year - 1987
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570240363
Subject(s) - nitrene , chemistry , intramolecular force , insertion reaction , photochemistry , irradiation , stereochemistry , organic chemistry , catalysis , physics , nuclear physics
A highly efficient intramolecular nitrene insertion was observed upon irradiation of 6‐azidouridine derivatives. The N 6 ,2′‐cyclo structure of the product was determined unequivocally by X‐ray crystallography.
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