Reduction of α,β‐unsaturated nitroalkenes with borane and borohydrides. A convenient route to 3‐nitro‐, 3‐hydroxylamino‐, and 3‐amino‐2h‐1‐benzopyran derivatives | Zendy

Varma Rajender S. | Zendy; Gai YuanZhu | Zendy; Kabalka George W. | Zendy

Premium

Reduction of α,β‐unsaturated nitroalkenes with borane and borohydrides. A convenient route to 3‐nitro‐, 3‐hydroxylamino‐, and 3‐amino‐2h‐1‐benzopyran derivatives

Author(s) -

Varma Rajender S.,

Gai YuanZhu,

Kabalka George W.

Publication year - 1987

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570240343

Subject(s) - chemistry , borane , nitro , borohydride , reduction (mathematics) , selective reduction , benzopyran , medicinal chemistry , catalysis , combinatorial chemistry , organic chemistry , alkyl , geometry , mathematics

The borohydride catalyzed borane reduction of 3‐nitrochromenes provided a facile route to a variety of 3‐hydroxylamino‐ 5 and 3‐amino‐2 H ‐1‐benzopyranes 6. Reduction with methoxyborohydride species, on the other hand, provided 3‐nitrochromans 2,4.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research