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Beckmann rearrangement of (+)‐3‐methoxy‐17‐methylmorphinan‐10‐one oxime
Author(s) -
Mohacsi Erno
Publication year - 1986
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570230655
Subject(s) - chemistry , beckmann rearrangement , oxime , organic chemistry , medicinal chemistry
(+)6,7,7a,8,9,10,11,11a‐Octahydro‐2‐methoxy‐12‐methyl‐5 H ‐7,11a‐irninoethanodibenz[ c, e ]azepin‐5‐one ( 3 ) was prepared by Beckmann rearrangement of the oxime of (+)‐3‐methoxy‐17‐methylmorphinan‐10‐one ( 2 ) with polyphosphoric acid.