Synthesis of new  N ‐aminoaziridine derivatives by the addition of dibenzyloxycarbonylaminonitrene to olefins | Zendy

Milcent René | Zendy; GuevrekianSoghomoniantz Marina | Zendy; Barbier GÉO | Zendy

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Synthesis of new N ‐aminoaziridine derivatives by the addition of dibenzyloxycarbonylaminonitrene to olefins

Author(s) -

Milcent René,

GuevrekianSoghomoniantz Marina,

Barbier GÉO

Publication year - 1986

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570230647

Subject(s) - chemistry , nitrene , cleavage (geology) , ring (chemistry) , order (exchange) , medicinal chemistry , organic chemistry , stereochemistry , catalysis , geotechnical engineering , fracture (geology) , engineering , finance , economics

In order to study the ring expansion of N ‐aminoaziridines into N ‐amino‐5‐membered heterocycles, N ‐(dibenzyloxycarbonylamino)aziridines were synthesized. N, N ‐Dibenzyloxycarbonylhydrazine was prepared. It was then oxidized with lead tetraacetate to a new diacylaminonitrene. This nitrene was added to various olefins to give the corresponding N ‐protected aminoaziridines. Cleavage of the protecting groups was realized for one example.

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