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Proton‐Ionizable crown compounds. 7 . Synthesis of new crown compounds containing the dialkylhydrogenphosphate moiety
Author(s) -
Bradshaw Jerald S.,
Huszthy Peter,
Izatt Reed M.
Publication year - 1986
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570230613
Subject(s) - chemistry , moiety , hydrolysis , alkali metal , zinc , crown (dentistry) , metal , polymer chemistry , phosphorus , organic chemistry , medicine , dentistry
A new series of macrocyclic ligands containing the dialkylhydrogenphosphate moiety is reported. These compounds were prepared by reacting phosphorus oxychloride with the appropriate oligoethylene glycol followed by a hydrolysis step. One of these new macrocyclic compounds transported the alkali metal cations as well as lead, zinc and silver ions.
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