Electroorganic synthesis. Reductive alkylation of functionalized 1,2‐dithiole‐3‐thiones | Zendy

Darchen André | Zendy; Berthelot Pascal | Zendy; Vaccher Claude | Zendy; Viana M. Nazareth | Zendy; Debaert Michel | Zendy; Burgot Jean Louis | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Electroorganic synthesis. Reductive alkylation of functionalized 1,2‐dithiole‐3‐thiones

Author(s) -

Darchen André,

Berthelot Pascal,

Vaccher Claude,

Viana M. Nazareth,

Debaert Michel,

Burgot Jean Louis

Publication year - 1986

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570230569

Subject(s) - chemistry , alkylation , yield (engineering) , electrosynthesis , alkyl , nuclear magnetic resonance spectroscopy , medicinal chemistry , spectroscopy , acetonitrile , organic chemistry , electrochemistry , catalysis , materials science , physics , electrode , quantum mechanics , metallurgy

Two‐electron reduction of some substituted 1,2‐dithiole‐3‐thiones 1 followed by alkylation of the dianionic intermediates leads through electrosynthesis to mixture of Z and E isomers of the corresponding substituted alkyl‐(3‐thioalkyl)‐2‐propenedithioates 2, 3 in satisfactory yield. The structure of those products was established by 13 C and 1 H nmr and mass spectroscopy. The isomers ratios were determined by nmr spectroscopy.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research