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Macrocyclic polyether‐ and polythioether‐diesters and dithioesters from 1,10‐phenanthroline‐2,9‐dicarboxylic acid
Author(s) -
Chandler Christopher J.,
Deady Leslie W.,
Reiss James A.
Publication year - 1986
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570230511
Subject(s) - chemistry , phenanthroline , pyridine , dicarboxylic acid , polymer chemistry , nuclear magnetic resonance spectroscopy , organic chemistry , medicinal chemistry
The synthesis of nine macrocyclic polyether‐ and polythioether‐diesters 9–13 and dithioesters 14–17 derived from 1,10‐phenanthroline‐2,9‐dicarboxylic acid are reported. The macrocycles were prepared under conditions of high dilution in the absence of metal templates in consistently good yields and their structures were confirmed by 1 H and 13 C nmr spectroscopy. A macrocyclic phenanthroline‐pyridine tetraester 18 is also recorded.