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1‐Azadienes in heterocyclic synthesis. Reaction of 1‐ N ‐alkyl‐1‐azapenta‐1,3‐dienes with mesoionic oxazolones
Author(s) -
Sain B.,
Sandhu J. S.
Publication year - 1986
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570230407
Subject(s) - mesoionic , chemistry , cycloaddition , alkyl , organic chemistry , double bond , medicinal chemistry , catalysis
1‐ N ‐Alkyl‐1‐azapenta‐1,3‐dienes 2 smoothly reacted with various mesoionic oxazolones 1 to afford 3,4‐di‐hydro‐2‐pyridones 3 in excellent yields and there was no evidence for the formation of any products arising from the cycloaddition on the carboncarbon double bond or on the azomethine function.

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