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Imino‐bridged heterocycles. IV . A facile synthesis of sulfenimines derived from diaryl ketones
Author(s) -
Brenner Daniel G.,
Cavolowsky Kathleen Mensler,
Shepard Kenneth L.
Publication year - 1985
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570220338
Subject(s) - chemistry , titanium tetrachloride , yield (engineering) , condensation , ammonia , titanium , organic chemistry , tetrachloride , combinatorial chemistry , materials science , physics , tin , metallurgy , thermodynamics
Efficient, high‐yield syntheses of N ‐diarylmethylene sulfenamides (sulfenimines) have been developed under mild laboratory conditions. Diaryl ketones have been shown to form ketimines readily by condensation with ammonia in the presence of titanium tetrachloride.