Premium
13 C NMR spectral assignments of chlorpromazine and its 5‐oxide. Literature correction
Author(s) -
Jovanovic Misa V.,
Biehl E. R.
Publication year - 1984
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570210604
Subject(s) - chemistry , coupling constant , chemical shift , allylic rearrangement , symmetry (geometry) , spectral line , oxide , carbon fibers , carbon 13 nmr , coupling (piping) , identity (music) , computational chemistry , stereochemistry , crystallography , organic chemistry , quantum mechanics , physics , mechanical engineering , materials science , geometry , mathematics , composite number , composite material , catalysis , acoustics , engineering
The 13 C chemical shift assignments of title compounds were made on the basis of their coupled and decoupled spectra. The size of the ipso and allylic 13 CH coupling constants establish unequivocally the identity of symmetry related carbon pairs and show that several assignments reported previously are incorrect.