Eight‐membered organosulfur heterocycles. Synthesis of dibenzo[ d,g ][1,3,6,2]dioxathiaphosphocin and dibenzo[ d,g ][1,3,6,2]dioxathiasilocin ring systems | Zendy

Pastor Stephen D. | Zendy; Spivack John D. | Zendy; Steinhuebel Leander P. | Zendy

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Eight‐membered organosulfur heterocycles. Synthesis of dibenzo[ d,g ][1,3,6,2]dioxathiaphosphocin and dibenzo[ d,g ][1,3,6,2]dioxathiasilocin ring systems

Author(s) -

Pastor Stephen D.,

Spivack John D.,

Steinhuebel Leander P.

Publication year - 1984

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570210508

Subject(s) - chemistry , ring (chemistry) , organosulfur compounds , aryl , alkyl , medicinal chemistry , alcohol , stereochemistry , organic chemistry , sulfur

The reaction of 2,2′‐thiobisphenols with either phenylphosphonous dichloride or phosphorus trichloride followed by an alcohol gave derivatives of the dibenzo[ d,g ][1,3,6,2]dioxathiaphosphocin ring system. The analogous reaction of 2,2′‐thiobisphenols with alkyl and aryl dichlorosilanes gave the heretofore unreported dibenzo[ d,g ][1,3,6,2]dioxathiasilocin ring system. The analytical and spectral data are reported.

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