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Eight‐membered organosulfur heterocycles. Synthesis of dibenzo[ d,g ][1,3,6,2]dioxathiaphosphocin and dibenzo[ d,g ][1,3,6,2]dioxathiasilocin ring systems
Author(s) -
Pastor Stephen D.,
Spivack John D.,
Steinhuebel Leander P.
Publication year - 1984
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570210508
Subject(s) - chemistry , ring (chemistry) , organosulfur compounds , aryl , alkyl , medicinal chemistry , alcohol , stereochemistry , organic chemistry , sulfur
The reaction of 2,2′‐thiobisphenols with either phenylphosphonous dichloride or phosphorus trichloride followed by an alcohol gave derivatives of the dibenzo[ d,g ][1,3,6,2]dioxathiaphosphocin ring system. The analogous reaction of 2,2′‐thiobisphenols with alkyl and aryl dichlorosilanes gave the heretofore unreported dibenzo[ d,g ][1,3,6,2]dioxathiasilocin ring system. The analytical and spectral data are reported.