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Reaction of glyceraldehyde with aryl and alkyl chloroformates
Author(s) -
Podraza Kenneth F.
Publication year - 1984
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570210454
Subject(s) - chemistry , aryl , alkyl , glyceraldehyde , medicinal chemistry , organic chemistry , dehydrogenase , enzyme
A number of 2,5‐bis(aryl‐ and alkyloxycarbonyloxymethylene)‐3,6‐bis(aryl‐ and alkoxycarbonyloxy)‐1,4‐dioxanes 5a‐d have been prepared by the reaction of glyceraldehyde with aryl and alkyl chloroformates. Bis aryl carbonates were also formed under certain conditions in this reaction. Nuclear magnetic resonance analysis of 5c indicated that it existed in a chair conformation with all the substituents in an equatorial position.