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1,3‐dipolar cycloaddition of methyl 3‐(1‐imidazolyl)acrylate and related compounds
Author(s) -
Kashima Choji,
Tsuzuki Atsushi,
Tajima Tadakuni
Publication year - 1984
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570210140
Subject(s) - chemistry , cycloaddition , moiety , acetonitrile , 1,3 dipolar cycloaddition , methyl acrylate , double bond , acrylate , medicinal chemistry , oxide , stereochemistry , organic chemistry , catalysis , monomer , polymer
The 1,3‐dipolar cycloaddition reaction of 1‐vinylimidazole and β‐(1‐imidazolyl)‐α,β‐unsaturated carboxylic esters with N.α ‐diphenylnitrone and acetonitrile oxide was carried out and compared with those of β‐pyrrolidinyl‐ and β‐phenyl‐α,β‐unsaturated carboxylic esters. The imidazolyl moiety bonded to olefinic double bond was suggested to have properties intermediate to pyrrolidinyl and phenyl groups.