Synthesis of substituted 3‐nitroso‐2,4‐pyridinediols for use as analytical reagents | Zendy

Leard Robert E. | Zendy; Bedenbaugh John H. | Zendy; Bedenbaugh Angela O. | Zendy

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Synthesis of substituted 3‐nitroso‐2,4‐pyridinediols for use as analytical reagents

Author(s) -

Leard Robert E.,

Bedenbaugh John H.,

Bedenbaugh Angela O.

Publication year - 1983

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570200541

Subject(s) - chemistry , reagent , nitroso , nitro , nitroso compounds , solvent , organic chemistry , solvent extraction , extraction (chemistry) , metal ions in aqueous solution , carboxylic acid , metal , nitro compound , medicinal chemistry , alkyl

The 5‐bromo, 5‐iodo, and 5‐nitro derivatives of 6‐methyl‐3‐nitroso‐2,4‐pyridinediol were synthesized and shown to produce colored complexes with a number of Group VIII metal ions. Also synthesized were the 1‐pentyl and 1‐octyl esters of 4,6‐dihydroxy‐5‐nitrosopyridine‐3‐carboxylic acid. These compounds showed potential as solvent extraction reagents for certain Group VIII metals.

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