Premium
Reaktionen von elektronenreichen heterocyclen mit orthocarbonsäure‐derivaten. I. Zum reaktionsverhalten von acyclischen orthoestern mit indolen unter säurekatalyse
Author(s) -
Akgün E.,
Pindur U.,
Müller J.
Publication year - 1983
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570200530
Subject(s) - chemistry , reactivity (psychology) , medicinal chemistry , medicine , alternative medicine , pathology
By kinetic controlled reaction of alkoxycarbenium‐ions 1a‐1d , generated in the medium, with the indoles 2a‐2c the methanes 3 , 4 or the ketones 5 and 6 are the single products. In the reaction with 1d the minimum of reactivity is achieved. The experimental condition of the reactions allow an estimation of the reactivity of 1a‐1d and 2a‐2c .